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Umrechnung NaOH 1/3 N auf 0,1 N ???
#1
Hallo Zusammen,

heute mal eine etwas

chemische Frage: :nixwiss

Die Konzentration der sauren Reinigungslösung soll per

Titration ermittelt werden. Es sollen 10 ml Lösung mit 0,1 N NaOH titriert werden

(Farbumschlag Phenolphthalein). Verbrauch in ml * Faktor = Gew.% bzw. Vol.% (je nach

Faktor).

Wir haben nur 1/3 N NaOH in Gebrauch und für diese wöchentliche Titration

will ich nicht unbedingt noch 0,1 N NaOH anschaffen.

Nachdem es 0,33333 N NaOH ist,

kann ich schlecht 3,33333 mal so viel saure Reinigungslösung vorlegen, so "krumme" Pipetten

gibt es ja gar nicht!

Kann ich den Verbrauch an NaOH einfach (per Dreisatz 1/3 * x =

0,1) mit einem zweiten Faktor (in diesem Fall 0,3) multiplizieren?? :hm


So

richtig schlecht war ich in Chemie zwar nicht und ich glaube auch, dass meine Rechnung

richtig ist, aber wozu habe ich Euch??


DANKE!!!!!!!
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#2
sorry, ich muß passen!
Gruß andrea
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#3
Meine Chemie liegt auch lange zurück aber ich versuch es

mal.
Ich würde aus 1/3N NaOH 0,1N NaOH herstellen.

Wie macht man das?

Wenn

ich logisch rangehe, sieht das so aus:

1/3N NaOH = 1 Teil 1N NaOH + 2 Teile

Wasser
0,1N NaOH = 1 Teil N NaOH + 9 Teile Wasser

von 1/3N zu 0,1N = 3 Teile 1/3N

+ 7 Teile Wasser
ich hab also wieder 10 Teile und einer davon ist 1N NaOH - also 1/10N

oder 0,1N NaOH.
Mit anderen Worten 3 ml 1/3N NaOH mit 7ml Wasser verdünnen.

Rein

rechnerisch würde ich deiner Annahme zustimmen.
Da in Eurer 1/3N NaOH 3,3333... mal mehr

NaOH drin ist als in 0,1N, sollte man den Verbrauch auch mit 0,3 multiplizieren

können.

Gruß
Anton
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#4
Hallo Anton,

danke Dir fürs Nachrechnen.
Nachdem jetzt einige Leute meine Theorie

geteilt haben, werde ich wenn die erste Lieferung da ist, einen Laborversuch starten: ich

werde eine Verdünnung der Säure herstellen (natürlich bekannter, d.h. errechneter und per

Leitfähigkeit überprüfter Konzentration) und einfach mal mit 1/3 N NaOH drauf los

titrieren.

Werde dann beizeiten Erfolg oder Mißerfolg

verkünden.

LG
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#5
Also mit dem

Rechnen scheint es bei uns allen nicht so weit her zu sein...

Die Grundüberlegung

war richtig, nur muss es nicht *0,3 sondern *3 heißen!!! Dann klappt es!

Danke Euch

trotzdem!!!

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#6
Wir

können schon rechnen, nur nicht denken <!-- sBig Grin --><img src="{SMILIES_PATH}/icon_biggrin.gif" alt="Big Grin" title="Very Happy" /><!-- sBig Grin -->
Was hat schon meine Mathelehrerin in der 4.

Klasse beim Umrechnen gesagt:
"Wird die Einheit kleiner wird die Zahl

größer."

Gruß
Anton
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